ON THE QUESTION OF ASSESSING FIRE HAZARD INDICATORS OF POLYMERIC MATERIALS BY THE METHOD OF SYNCHRONOUS THERMAL ANALYSIS

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Страницы 51–63
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Oksana V. Bezzaponnaya1, Alexey V. Kozionov2, Evgeniy V. Vakarin1, Omar G. Magomedov1
1 Ural Institute of State Fire Service of EMERCOM of Russia, Russian Federation
2 Forensic Institution of the Federal Fire Service "Fire Testing Laboratory" of Sverdlovsk Region, Yekaterinburg, Russian Federation

Аннотация. 

 materials of various chemical natures using the STA "Netzsch" 449 F 5 Jupiter thermal analyzer are presented. The feasibility of assessing the autoignition temperature using three analytical signals simultaneously is demonstrated: differential scanning calorimetry, differential the rmogravimetry, and the first derivative of differential scanning calorimetry. To diagnose the autoignition temperature using the synchronous thermal analysis method, the following conditions must be met: being in the temperature range of the exothermic peak of thermooxidative destruction of the polymer; proximity to the inflection point on the DSC-curve; proximity to the maximum of the DTG-peak; maximum heat release intensity.
The problem of assessing the heat of combustion of substances and materials is also considered. To enhance the practical significance of heat of combustion assessment results, a method for assessing the heat of combustion using synchronous thermal analysis in an oxidizing air environment is proposed, taking into account the results of testing the material under study in an inert atmosphere.

Ключевые слова: fire safety, polymeric materials, autoignition temperature, synchronous thermal analysis method
Для цитирования: 

On the question of assessing fire hazard indicators of polymeric materials by the method of synchronous thermal analysis / O. V. Bezzaponnaya et al. // Technospheric safety. 2025. № 4 (49). Pp. 51–63.